Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Oxidation of Hydrazobenzene by Oxygen Catalysed by Co (3MeOsalen) in Methanol

  • Homer Roger B. (School of Chemical Sciences, University of East Anglia) ;
  • Cannon Roderick D. (School of Chemical Sciences, University of East Anglia) ;
  • Kim Stephen S.B. (Department of Chemistry, University of Ulsan)
  • Published : 1985.04.20
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Abstract

The oxidation of hydrazobenzene by oxygen in methanol solution is catalysed by Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and oxygen has been proposed.

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References

  1. Justus Liebigs Ann. Chem. v.503 P. Pfeiffer;E. Breith;E. Lubbe;T. Tsumaki
  2. Chem. Rev. v.79 R. D. Jones;D. A. Summerville;F. Basolo
  3. Brit. Med. Bull. v.32 M. F. Perutz
  4. Coord. Chem. Rev. v.39 T. D. Smith;J. R. Pilbrow
  5. Acc. Chem. Res. v.13 R. S. Drago;B. B. Corden
  6. J. Gen. Chem. USSR v.44 A. V. Savitskii
  7. J. Amer. Chem. Soc. v.103 A. Zombeck;R. S. Drago;B. B. Corden;J. H. Gaul
  8. Inorg. Chim. Acta v.44 S. Nemeth;Z. Szeverenyi;L. I. Simandi
  9. Justus Liebigs Ann. Chem. v.316 W. Manchot;J. Herzog
  10. J. Amer. Chem. Soc. v.54 J. H. Walton;G. W. Filson
  11. Chem. Ber. v.101 G. Kaupp;G. A. Russell
  12. Inorg. Chem. v.13 L. Rosenhein;D. Speiser;A. Haim
  13. Iowa State Coll. Jour. Science v.22 H. Diehl;L. M. Ligget;C. C. Hach;G. C. Harrison;L. Henselmeier;R. W. Schwant;J. Mathews, Jr.
  14. Ph. D. Thesis, University of East Anglia M. A. Beckett
  15. Helv. Chim. Acta v.43 F. Gerson;E. Heilbronner;A. van Veen;B. M. Wepster

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