Korean Journal of Agricultural Science (농업과학연구)
- Volume 11 Issue 1
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- Pages.176-181
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- 1984
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- 2466-2402(pISSN)
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- 2466-2410(eISSN)
Linear Free Energy Relationship on the Phosphorylation of Acetylcholinesterase by Insecticidal O,O-Diethylphenylphosphate Derivatives
살충성(殺蟲性) O,O-Diethylphenylphosphate유도체(誘導體)들에 의(依)한 Acetylcholinesterase의 Phosphorylation에 미치는 자유(自由)에너지 관계(關係)
- Sung, Nack-Do (Department of Agricultural Chemistry, College of Agriculture, Chungnam National University)
- 성낙도 (충남대학교 농과대학 농화학과)
- Published : 1984.06.30
Abstract
Linear free energy relation ship(LFER) on the insecticidal activity of O,O-diethylphenylphosphate (A) and 3,5-dimethylphenyl-O,O-diethylphosphate (B) derivatives were studied by EHT MO calculation method and regression analysis method. LFER between varying substituent constants and
살충성 O,O-diethylphenylphosphate (A)와 3,5-dimethylphenyl-O,O-diethylphosphate 유도체 (B)에 의한 acetylcholinesterase(Ach E)의 phosphorylation 반응에 미치는 정량적인 자유에너지 관계(LFER)를 알아보기 위하여 Ach E의 두 작용점인 esteratic-anionic site에 대응하는 (A) 및 (B)의 P원자 및 meta 위치간의 공간직선 거리 및 알짜전하를 확장 H
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