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A Short Synthesis of (Z)-13-Eicosen-10-one the Principal Component of the Peach Fruit Moth Pheromone

  • Lee, Eun (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Koh, Soo-Young (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Song, Byong-Doo (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Park, Tae-Kyo (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • Published : 1984.12.20

Abstract

(Z)-13-Eicosen-10-one (1), one of the active components of the female pheromone of the peach fruit moth, Carposina niponensis Walsingham, was synthesized from 2-nonanone, succinic anhydride, and n-nonyllithium. The key step involves the preparation of 13-eicosyn-10-one from an epoxyketone via Eschenmoser cleavage.

Keywords

References

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Cited by

  1. ChemInform Abstract: A SHORT SYNTHESIS OF (Z)-13-EICOSEN-10-ONE THE PRINCIPAL COMPONENT OF THE PEACH FRUIT MOTH PHEROMONE vol.16, pp.25, 1984, https://doi.org/10.1002/chin.198525372
  2. Direct amino acid-catalyzed cascade biomimetic reductive alkylations: application to the asymmetric synthesis of Hajos–Parrish ketone analogues vol.6, pp.22, 1984, https://doi.org/10.1039/b807999d
  3. Fe-Catalyzed Synthesis of (13Z)-Eicos-13-en-10-one, the Main Sex Pheromone Component of Carposina niponensis vol.53, pp.1, 1984, https://doi.org/10.1007/s10600-017-1925-3