Bulletin of the Korean Chemical Society

  • 제5권6호
  • /
  • Pages.211-215
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  • 1984
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Reactions of Thianthrene Cation Radical Perchlorate with Free Radical. Ⅱ. On the Reaction with tert-Butyl Peroxide$^1$

  • 발행 : 1984.12.20
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초록

Reaction of thianthrene cation radical perchlorate (1) with tert-butyl peroxide (TBP) in acetonitrile gave thianthrene (2), thianthrene 5-oxide (3), cis-thianthrene-5,10-dioxide (4), 5-acetonylthianthrenium perchlorate (9), along with small amount of thianthrene-5,5-dioxide (7) in some cases. Isolation of N-tert-butylacetamide indicated the formation of tert-butyl cation from TBP. The formation mechanisms of these products were proposed.

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참고문헌

  1. M.S. Thesis Protions of this work are abstracted J.H. Shin
  2. Proc. Coll. Natur. Sci. v.2 K. Kim
  3. STF-77-38 K. Kim;N.C. Jeong
  4. J. Org. Chem. v.28 The formation of 4 the been isolated from the reaction of 1 with diethylmercury
  5. Bull. Korean Chem. Soc. v.1 H-J. Lee;K. Kim
  6. Can. J. Chem. v.36 D. E. McElcheran;M. H. J. Wijnen;E. W. R. Steacie
  7. J. Phys. Chem. v.69 E. T. Kaiser;D. H. Eargle, Jr.
  8. J. Amer. Chem. Soc. v.86 K. Mislow;P. Schneider;A. L. Ternay, Jr.
  9. Chem. and Ind. R. Stewart;L. J. Muenster
  10. J. Org. Chem. v.40 K. Kim;S. R. Mani;H. J. Shine
  11. Ber. v.65 E. Bergman;M. Tschudnowshy
  12. Free-Radical Chain Reactions E. S. Huyser
  13. J. Amer. Chem. Soc. v.90 J. A. Howard;K. U. Ingold
  14. Bull. Chem. Soc. Jap. v.36 K. Tokumaru;O. Simmamura
  15. J. Amer. Chem. Soc. v.83 H. Tsubomura;R. P. Lang
  16. The Chemistry of the Sulphonium Group H. J. Shine;C. J. M. Stirling(ed.)
  17. J. Amer. Chem. Soc. v.93 C. S. Foots;J. W. Peters
  18. J. Amer. Chem. Soc. v.89 K. F. Purcell;J. R. Berschied, Jr.
  19. J. Amer. Chem. Soc. v.102 W. Ando;Y. Kabe;S. Kobayashi;C. Takyu;A. Yamagishi;H. Inaba

피인용 문헌

  1. New Mechanism for the Reaction of Thianthrene Cation Radical Perchlorate with tert-Butyl Peroxide vol.23, pp.1, 1984, https://doi.org/10.5012/bkcs.2002.23.1.103