Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reactions of Thianthrene Cation Radical Perchlorate with Free Radical. Ⅱ. On the Reaction with tert-Butyl Peroxide$^1$

  • Published : 1984.12.20
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Abstract

Reaction of thianthrene cation radical perchlorate (1) with tert-butyl peroxide (TBP) in acetonitrile gave thianthrene (2), thianthrene 5-oxide (3), cis-thianthrene-5,10-dioxide (4), 5-acetonylthianthrenium perchlorate (9), along with small amount of thianthrene-5,5-dioxide (7) in some cases. Isolation of N-tert-butylacetamide indicated the formation of tert-butyl cation from TBP. The formation mechanisms of these products were proposed.

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References

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Cited by

  1. New Mechanism for the Reaction of Thianthrene Cation Radical Perchlorate with tert-Butyl Peroxide vol.23, pp.1, 1984, https://doi.org/10.5012/bkcs.2002.23.1.103