Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reactions of Oxomolybdenum (Ⅴ) with the 17-tungsto-2-phosphate Anion

  • Published : 1984.08.20
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Abstract

Reactions of $MoOCl_5^{2-}$ with ${\alpha}_2-[P_2W_{17}O_{61}]^{10-}$ have been studied spectrophotometrically and several complexes have been identified. The transient species initially formed is probably $[Mo_2O_4(P_2W_{17}O_{6l})_2]^{18-}$. At $pH {\le} 3$the visible spectrum changes gradually, indicating formation of a transient isomer of $[P-2Mo^VW_{17}O_{62}]^{7-}$, which again transforms into the stable isomer. The transient isomer absorbs light much more strongly than the stable isomer in the visible range. At $pH > 3 [P_2W^VW_{16}O_{61}]^{11-}$ is formed probably via the transient isomer of $[P_2Mo^VW_{17}O_{61}]^{7-}$.

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References

  1. Bull. Korean Chem. Soc. v.5 Y. H. Cho;H. So
  2. Inorg. Chem. v.1 C. R. Hare;I. Bernal;H. B. Gray
  3. J. Coord. Chem. v.9 H. So;M. Kolor;P. R., Robinson;G.P. Haight, Jr.;R.L. Belford
  4. Inorg. Chem. v.15 T. Imamura;J. P. Haight, Jr.;R. L., Belford
  5. Inorg. Chem. v.9 G. M. Varga, Jr.;E. Papaconstantinou;M. T. Pope
  6. Inorg. Chem. v.15 R. A. Prados;M. T. Pope
  7. J. Chem. Res., Synop. 222 R. Contant;J.-P. Ciabrini
  8. J. Inorg. Nucl. Chem. v.38 J. M., Fruchart;G. Herve;J. P. Lunay;Massart
  9. J. Amer. Chem. Soc. v.104 C. Sanchez;J. Livage;J. P. Launay;M. Fournier;Y. Jeannin
  10. J. Inorg. Nucl. Chem. v.43 R. Contant;J.-P. Ciabrini
  11. J. Amer. Chem. Soc. v.105 S. P. Harmalker;M.A. Leparulo;M. T. Pope
  12. J. Chem. Res., Synop. R. Contant;J.-P. Ciabrini
  13. J. Chem. Res. Miniprint R. Contant;J.-P. Ciabrini
  14. Ions Mineraux Condenses P. Souchay
  15. Inorganic Syntheses v.15 H. K. Saha;A. K. Banerjee
  16. Inorg. Chem. v.14 J. J. Altenau;M. T. Pope;R. A. Prados;H. So
  17. Inorg. Chem. v.11 H. So;M. T. Pope