A Study on the Tungstate-Sensing Electrodes

Tungstate Ion 감응 전극에 관한 연구

  • Gwon-Shik Ihn (Department Chemistry, Keimyung University) ;
  • Jung-hwa Lee (Department of Chemistry, Sejong College) ;
  • R. P. Buck (Department of Chemistry, University of North Carolina)
  • 인권식 (계명대학교 자연과학대학 화학과) ;
  • 이중화 (세종대학교 화학과) ;
  • Published : 1983.04.20

Abstract

Three component $Ag_2S-PbS-PbWO_4$ electrodes have been prepared and evaluated for sensitivity to tungstate. The 51.71 : 16.64 : 31.65(w/w%) composition is superior in terms of potentiometric response, stability, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}~10^{-4}M WO_4^{2-}$ in $0.1F-NH_4Ac-NH_4OH$ buffer at pH 8.00 with constant ionic strength. The quality of response is similar to that of corresponding phosphate-sensing electrode. Many common ions interfere.

Tungstate 이온 감응에 대하여 세가지 성분인 $Ag_2S-PbS-PbWO_4$로된 전극이 제조되어 평가 되었다. 성분비(w/w%)가 51.71 : 16.64 : 31.65인 전극이 전위차 감응, 안정도, 감응속도, 감응속도, 재현성이 우수 하였다. $0.1F-NH_4Ac-NH_4OH$ 완충용액 속에서 일정한 이온강도와 pH 8.00로 조정된 $10^{-1}~10^{-4}M WO_4^{2-}$ 농도범위에서 실험하였고 감응성은 phosphate 감응 전극과 비슷하였다. 많은 이온들이 방해를 하였다.

Keywords

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