The Dependence of Electrical Conductivity of Cupric Oxide on Temperature

산화동에 있어 온도변화에 의한 전기전도도에 관한 연구

  • 안영필 (한양대학교 무기재료공학과) ;
  • 이희동 (한양대학교 무기재료공학과)
  • Published : 1983.02.01

Abstract

We studied the dependence of electrical conduction mechanism of Cupric Oxide on temperature and measured the specific resistivity of sintered specimen from $600^{\circ}C$ to 90$0^{\circ}C$ . We considered the relations between electrical conducti-vityand temperature with reheating the sintered specimen. X-Ray diffraction patterns showed that lattice parameters of cupric oxide increased above 20$0^{\circ}C$. Cupric oxide had nostoichiometric compositions$(CuO_{1+x})$ owing to the excess oxygen and showed hole conduction with energy gap of 0.15eV below $650^{\circ}C$$\pm$1$0^{\circ}C$ Above $650^{\circ}C$$\pm$1$0^{\circ}C$ cupic oxide had the stoichiometric composition and showed electron-hole conduction owing to the intrinsic ionization with energy gap of 1.04V.

Keywords

References

  1. Crystal structure of minerals
  2. Contemp. Phys v.11 no.5 Magnetic semiconductor
  3. The magnetochemistry and stoichiometry of the copper-Oxygen System M. O. 'keeffe;F. S. stone
  4. surface sci v.33 no.1 Characterization of oxygen species absorbed on copper and nickel oxide by X-ray photoelectron specrroscopy T. Robert;M. Bartel;G. Offergeld
  5. J. Phys. Soc. Japan v.18 no.Supply 2 The defect structure of CuO M. O'keeffe;Yukiko Ebisuzaki;Walter J. Moore
  6. Ann Physik v.7;7 no.55;70 The semiconducting, Property of cuprous oxide K. Stecker
  7. Nonstoichiometry diffusion and electrical conductivity in binary metal oxide Per Kofstad
  8. Solid state comn v.9 Band structure and the sakeup photoelectron spectra of copper and nickel hallide and oxide T. Novakov;R. Prins