한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제20권1호
  • /
  • Pages.3-12
  • /
  • 1983
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지

졸-겔법에 의한 $Al_2O_3$.$2SiO_2$ 유리의 제조

Preparation of $Al_2O_3$.$2SiO_2$ glass by the sol-gel process

  • 이준 (인하대학교 공과대학 무기재료공학과) ;
  • 지응업 (아주대학교 공과대학 화학공학과) ;
  • 조동수 (인하대학교 공과대학 무기재료공학과)
  • Rhee, Jhun (Dept. of Ceramic Eng., Inha Univ) ;
  • Chi, Ung-Up (Dept. of Chemical Eng., Ajou Univ) ;
  • Jo, Dong-Soo (Dept. of Ceramic Eng., Inha Univ)
  • 발행 : 1983.01.01
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초록

In the present study an attempt was made to synthesize the $Al_2O_3$.$2SiO_2$ glass in which atomic ratio is Al:Si=1:1 by sol-gel process. And at such a low temperature as 55$0^{\circ}C$ clear amorphous gel derived glass with Si-O-Al bonding was obtained. $Si(OC_2H_5)_4$ and $Al(NO_3)_3$.$9H_2O$ were used as the precursor and among the mutual solvents only n-butanol gave good results for the synthesis of the gel derived glass. Partial hydrolysis of TEOS with one-fold mol of $H_2O$ prior to the reaction with aluminum nitrate gave the better results., Total oxide content to the total reactants by weight was affective to the results.

키워드

참고문헌

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