Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Calculation of the Magnetic Moments and the Dipolar Shifts for d$^1$ and d$^2$Complexes in a Strong Ligand Field of Trigonal Symmetry

  • Ahn, Sang-Woon (Department of Chemistry, Jeonbug National University) ;
  • Suh, Hyuk-Choon (Department of Chemistry, Jeonbug National University) ;
  • Ko, Jeong-Soo (Department of Chemistry, Mogpo National College)
  • Published : 1982.09.30
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Abstract

A method to calculate the magnetic moments for $d^1$ and $d^2$ complexes in a strong crystal field of trigonal symmetry has been developed in this work choosing the trigonal axis (Ⅲ) as the quantization axis. The calculated magnetic moments using this method for $d^1$ and $d^2$ complexes in a strong trigonal ligand field fall in the range of the experimental values. The dipolar shifts for $d^1$ and $d^2$ complexes in a strong trigonal ligand field are also calculated using the calculated magnetic susceptibility components. The calculated values of the dipolar shifts also fall in the reasonable range.

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References

  1. Magnetism and Transition Metal Complexes F. E. Mabbs;D. J. Machin
  2. Theory and Application of Molecular Paramagnetism E. A. Boudreaux;L. N. Mulay
  3. Some Aspect of Crystal Field Theory T. M. Dunn;D. S. McClure;R. G. Pearson
  4. J. Korean Chem. Soc. v.24 S. Ahn;E. Park;B. B. Park
  5. J. Chem. Phys. v.29 H. M. McConnell;R. E. Robertson
  6. Introduction to Ligand Field Theory C. J. Ballhausen
  7. Thesis Ph. D. The University of New South Wales L. C. Stubbs
  8. Basic Principles of Ligand Field Theory H. L. Schalfer;G. Gliman
  9. J. Chem. Soc. (A) D. J. Machin;K. S. Murray
  10. Lecture Note on Ligand Field Theory C. J. Ballhausen
  11. S. Ahn
  12. Applied Wave Mechanics R. M. Golding
  13. Theory and Applications of Molecular Paramagnetism E. A. Boudreaux;L. N Mulay
  14. Progr. Inorg. Chem. v.22 S. Mitra
  15. Prog. Inorg. Chem. v.26 M. Geloch
  16. N. M. R. Spectroscopy v.6A G. A. Webb
  17. Coordination Chem. Revs. v.6 W. De. Horrocks, Jr.
  18. Mol. Phys. v.31 R. M. Golding;R. O. Pascual;L. C. Stubbs