Bulletin of the Korean Chemical Society

  • 제3권2호
  • /
  • Pages.76-78
  • /
  • 1982
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The Facile Synthesis of Pentane-1, 5-diamines from Glutaraldehyde and Secondary Amines with Tetracarbonylhydridoferrate

  • Shim Sang Chul (Department of Industrial Chemistry, Kyungpook National University) ;
  • Watanabe Yoshihisa (Department of Hydrocarbon Chemistry, Kyoto University)
  • 발행 : 1982.06.30
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초록

Ethanolic tetracarbonylhydridoferrate solution combined with glutaraldehyde is a very effective reducing agent for the selective transformation of two moles of secondary amines into pentane-1,5-diamine derivatives. A variety of aliphatic secondary amines react with ferrate-glutaraldehyde at room temperature under carbon monoxide to give the corresponding N-substituted pentane-1,5-diamines in reasonable yields.

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참고문헌

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