Bulletin of the Korean Chemical Society

  • 제3권2호
  • /
  • Pages.55-60
  • /
  • 1982
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Bromine-Exchange Reaction of Antimony Tribromide with Benzyl Bromide in Nitrobenzene and in 1,2,4-Trichlorobenzene$^*$

  • Choi Sang Up (Department of Chemistry, Sogang University) ;
  • Pae Young Il (Department of Industrial Chemistry, Ulsan Institute of Technology) ;
  • Rhyu Sok Hwan (Department of Industrial Chemistry, Ulsan Institute of Technology)
  • 발행 : 1982.06.30
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초록

The rate of the bromine-exchange reaction of antimony tribromide with benzyl bromide in nitrobenzene or 1,2,4-trichlorobenzene has been measured, using Br-82 labelled antimony tribromide. The result of the study indicates that the exchange reaction is first order with respect to benzyl bromide, and either second or first order with respect to antimony tribromide depending on its concentrations. The second-order kinetics with respect to antimony tribromide have been observed at relatively high $[SbBr_3]$ concentrations, and the first-order kinetics at lower $[SbBr_3]$ concentrations. Reaction mechanisms are proposed for the exchange reaction.

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참고문헌

  1. J. Amer. Chem. Soc. v.87 Sang Up Choi;J. E. Willard
  2. J. Phys. Chem. v.72 Oh Chun Kwon;Sang Up Choi
  3. J. Korean Chem. Soc. v.14 Sang Up Choi
  4. J. Korean Chem. Soc. v.20 Oh Chun Kwon;Sang Up Choi
  5. Bull. Korean Chem. Soc. v.2 Oh Chun Kwon;Young Cheul Kim;Sang Up Choi
  6. Bull. Korean Chem. Soc. v.2 Oh Chun Kwon;Young Cheul Kim;Sang Up Choi
  7. Young Il Pae;Sang Up Choi
  8. J. Korean Chem. Soc. v.9 K. H. Jung;Y. Huh;I. Lee
  9. Nuclear and Radiochemistry G. Friedlander;J. W. Kennedy;J. M. Miller

피인용 문헌

  1. The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide vol.240, pp.1, 1982, https://doi.org/10.1016/j.molcata.2005.06.011