Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Kinetics of Cl Atom Reactions. Anomaluous Fluorescence Behavior of Some Cl Atomic Transitions

  • Kwang-Yul Choo (Department of Chemistry, School of Natural Sciences, Seoul National University)
  • Published : 1980.03.30
Download PDF
⟨ Previous Next ⟩

Abstract

During the study of the kinetics of Cl atom reactions by atomic fluorescence method we observed anomalous fluorescence emission for some atomic transitions. Instead of usual decrease of the fluorescence intensity by adding substrate, 1363 A transition $(^2P^{\circ}_{3/2}{\to}^2P_{1/2})$ intensity increased by adding substrate. From the normally behaved fluorescence lines the absolute rate constant for the reaction, Cl + $CH_3Cl{\to}$, was found to be $4.2{\times}10^{-13}$ cc/molecule sec at $20^{\circ}C$.

Keywords

References

  1. J. Chem. Phys. v.50 R. J. Donovan;D. Husain;W. Braun;A. M. Bass;D. D. Davis
  2. J. Chem. Phys. v.70 J. V. Michael;D. F. Navam;W. A. Page;L. J. Stief
  3. Proc. Chem. Soc. G. Porter
  4. J. Phys. Chem. v.79 K. Y. Choo;P. P. Gaspar;A. P. Wolf
  5. J. Phys. Chem. v.82 D. J. Schlyer(et al.)
  6. Flame Emission and Atomic Absorption Spectroscopy v.2 A. Syty
  7. J. Chem. Phys. v.45 J. V. Michael;R. E. Weston
  8. J. Chem. Phys. v.45 A. Carrington;D. H. Levy;T. A. Miller
  9. Int. J. Chem. Kinetics v.2 D. D. Davis;W. Braun;A. M. Bass
  10. J. Amer. Chem. Soc. v.93 J. Connor;P. J. Young;O. P. Strausz