Studies on Xylan of Tropical Hardwood (I) Wood Analysis

열대산(熱帶産) 광엽수재(廣葉樹材)의 Xylan에 관(關)한 연구(硏究) (I) -목재분석(木材分析)-

Tropical hard wood produces a number of extracts, especially hot-water extracts. The lignin content in the two kinds of bangkirai and red lauan belonging to genus Shorea, was as high as in temperate zone soft wood, mangrove wood of genus Rhizophara contained it on the same level as temperate zone hard wood and keruing of genus Dipterocarpus was in between the two kinds of bangkirau and red lauan, and keruing wood. The xylose content of saccharose composition in the tree of genus Shorea, was as low as in needle-leaved trees, mangrove wood contained it on the same level as broad-leaved trees and the xylose content in keruing wood was in between the above two kinds of wood. The total retrieving rate of alditol acetate acetificated with sulphuric acid and acetic anhydride, did not reach 100%, even if it was supplemented. There was no difficulty in analyzing alditol immediately after acetification but, when it was left for four or five days, the acetificated alditol acetate was dissolved. The pyridine alditol acetificated with pyridine and acetic anhydride, showed the same result.

열대산(熱帶産) 광엽수재(廣葉樹材)에는 추출물(抽出物)이 많고, 특(特)히 온수추출물(溫水抽出物)이 많다. Lignin 함유량(含有量)은 Shorea속(屬)의 2수종(樹種)(Bangkirai, Red lauan)이 온대산(溫帶産) 침엽수재(針葉樹材)정도로 높고, Rhizophara속(屬)의 Mangrove재(材)는 온대산(溫帶産) 광엽수재(廣葉樹材)정도이며, Dipterocarpus속(屬)의 Keruing재(材)는 이것들의 중간(中間)정도이다. 당조성(糖組成)은 Xylose함유량(含有量)이 Shorca 속(屬)의 그 수종(樹種)이 온대산(溫帶産) 침엽수재(針葉樹材)정도로 낮고, Mangrove재(材)는 온대산(溫帶産) 광엽수재(廣葉樹材)정도이며, Kcruing재(材)는 이것들의 중간(中間)정도다. 황산(黃酸)과 무수초산(無水酢酸)에 의한 acctyl화(化)한 alditol acetate의 전수율(全收率)은 보정(補正)하여도 100%가 되지 않는다. Acetyl화(化)한 직후(直後)이면 분석(分析)에 지장이 없지만, 4~5일(日) 방치(放置)하면 분해(分解)가 일어난다. 그리고 Pyridine과 무수초산(無水酢酸)으로 acetyl환(化)한 것도 같은 경과(結果)였다.