약학회지 (YAKHAK HOEJI)
- 제19권2호
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- Pages.101-110
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- 1975
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- 0377-9556(pISSN)
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- 2383-9457(eISSN)
방향족 활성 Chloro화합물의 Alkoxy기 치환에 관한 연구
Stydies on the Substitution of the Activated Aromatic Chloride with Alkoxy Group.
초록
p-Chloronitrobenzene(substrate) and p-nitrophenetole (product) were quantitatively analyzed to know the degree of extent of reaction in the process of time. The calibration curve was prepared by the internal satndard method in gaschromatography. 2,6-Dimethyl-naphthalene was used as internal standard. The rate constant(k), the reaction velocity in various concentrations of NaOH altered, and the formation of byproducts(azo-compound and p-nitrophenol) with the amounts of MnO
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