Synergistic Effect of Citric Acid on Antioxidant Property of BHT

BHT (Butylated hydroxy toluene)의 항산화성(抗酸化性)에 대한 citric acid의 상승효과(相乘效果)

  • Lee, Hi-Bong (Department of Agricultural Chemistry, Chung Buk national university)
  • Published : 1975.06.30

Abstract

Relative retarding or pro-oxidant effect of 0.02% BHT, 0.01% citric acid and 0.1 ppm $CuSO_4$ $5H_2O$, on the peroxide value and the free fatty acid value development of two groups of edible soybean osils was studied. One group of the oils was stored in a dark place at $40{\pm}0.5^{\circ}C$, and the other group was irradiated 3 hours daily, with direct sunlight. The results of the study were as follow; 1. Peroxide value and free fatty acid value were, in general, more rapidly promoted in the case of the irradiated oils than in case of the oils stored in the dark place. 2. Peroxide value and free fatty acid value were rapidly increased in the case of the sample in addition to $CuSO_4$ $5H_2O $ in both caies. 3. Synergistic effect of citric acid on BHT was strong pronounced in both cases.

식용대두유(食用大豆油)에 0.02% BHT, 0.01% citric acid 및 0.1 ppm $CuSo_4\;5H_2O$를 단독 또는 혼합 첨가하여 암소저장조건하(暗所貯藏條件下)$(40{\pm}0.5^{\circ}C)$ 및 일사광선조사조건하(日射光線照射條件下)에서 저장(貯藏)하여 과산화물가(過酸化物價)와 유리지방산가(遊離脂肪酸價)의 변화(變化)를 측정하여 다음과 같은 결과(結果)를 얻었다. 1. 일반적(一般的)으로 일사광선조사조건(日射光線照射條件)에서는 암소저장조건(暗所貯藏條件)에서 보다 과산화물가(過酸化物價)와 유리지방산가(遊離脂肪酸價)가 빠른 속도로 상승하였다. 2. $CuSO_4{\cdot}5H_2O$를 첨가한 시료구(試料區)에서는 일사광선조건(日射光線條件)과 암소저허조건(暗所貯虛條件)에서 과산화물(過酸化物)과 유리지방산(遊離脂肪酸)을 강(强)하게 형성(形成)하였다. 3. BHT에 대한 citric acid의 상승효과는 암소저장조건(暗所貯藏條件)과 일사광선조건(日射光線條件)에서 모두 강(强)하게 나타났다.

Keywords