植物油 脫臭溜出物의 利用에 關한 硏究

Studies on the Utilization of Deodorized Condensates from Vegetable Oils

植物油 脫臭溜出物에 함유되어 있는 sterine과 tocopherol의 效率的인 分離精製方法을 검토하였다. 시료를 가열하여 水層과 油層으로 分離하고 油層을 取하여 메틸에스테르화한 후 脂肪酸을 溜去하였다. 殘油分을 비누화하여 불비누화분만을 抽出, 濃縮한 후 메틸알코올에 녹여, 냉각함으로서 sterine을 분리하였다. 위의 母液을 메틸알코올에 녹인 후 $-20^{\circ}C$ 냉각하여 遊離脂肪酸을 제거하고 이온交換樹脂로 처리하여 高濃度의 tocopherol을 얻는 조건을 확립하였다.

An investigation has been performed to find an effective separation method of steriols and tocopherols from the deodorized condensates of vegetable oils. Simple heating of the starting mixture isolated the oil layer from water, and the former was collected. It was then methyl esterified followed by a distillation for the removal of fatty acid. The ensuing step was to saponify the residue. The unsaponifiable matter was extracted by both methanol and concentrated. The sterol was crystallized by cooling such concentrated solution. To obtain tocopherol, the mother liquor was first dissolved in methanol. Cooling this solution to $-20^{\circ}C$ trapped fatty acid which was filtered out. The filtrate was then treated with ion exchange resin.