할라이드의 $S_N2$ 형 반응성에 미치는 술페닐, 술피닐 및 술포닐기의 효과에 대한 확장 Huckel 계산

Extended Huckel Calculations of the Effect of Sulfenyl, Sulfinyl and Sulfonyl Groups on the Reactivity of Halides in $S-N2$ Reactions

  • Ui Rak Kim (Department of Chemistry, Catholic Medical College) ;
  • Kyu Yong Lee (Department of Chemistry, Catholic Medical College) ;
  • Sun Ho Bai (Department of Chemistry, Catholic Medical College) ;
  • Ikchoon Lee (Department of Chemistry, Inha University)
  • 발행 : 1974.02.28

초록

확장 Huckel법을 사용하여 술페닐, 술피닐 및 술포닐기가 할라이드의 $S-N2$형 반응에 미치는 효과를 고찰하고 각종 반응성 지수를 비교, 검토한 결과 bond formation과정의 반응성 지수중 Frontier electron에 의한 것이 가장 합리적인 것임을 밝혔다.

Extended Huckel calculations have been carried out to study the effect of sulfenyl, sulfinyl and sulfonyl groups on the reactivity of halides in $S-N2$ reactions. Results indicate that the most reasonable reactivity index is that based on the Frontier electron for the bond formation process.

키워드

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