대한화학회지 (Journal of the Korean Chemical Society)

  • 제17권4호
  • /
  • Pages.286-297
  • /
  • 1973
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

Alicyclic 1,2-디할로폴리플루오르올레핀으로 부터 비닐리튬 화합물과 Perfluorinated 유기금속화합물의 합성

The Preparation of Perfluorinated Organometallic Compounds via Vinyllithium Compounds of Alicyclic 1,2-Dihalopolyfluoroolefins

  • 박달조 (미국 콜로라도대학교 화학과) ;
  • 최삼권 (미국 콜로라도대학교 화학과)
  • Joseph D. Park (Department of Chemistry, University of colorado, The Korea Advanced Institute of Science) ;
  • Choi Sam Kwon (Department of Chemistry, University of colorado, The Korea Advanced Institute of Science)
  • 발행 : 1973.08.30
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초록

폴리플루오로알켄닐리튬 化合物들이 1,2-dihalopolyfluorocycloalkenes와 알킬리튬試藥과의 交換反應에 依하여 合成되었다. 수은, 비소와 디메틸게르마늄할로겐화물과의 여러 가지 反應이 著述되어 있고 또 이 化合物들의 化學的性質에 대하여 考察하였다.

Polyfluorocycloalkenyllithium compounds have been prepared by exchange reaction with 1,2-dihalopolyfluorocycloalkenes and alkyllithium reagents. Their reactions with mercuric, arsenic and dimethyl germanium halides are described and the chemistry of these compounds discussed.

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