Abstract
When industrial wastewater containing fluoride runs into the ocean, approximately 0.1ppm of F$\^$-/ will react with seawater and will be eventually lost, and the remaining F$\^$-/ can be determined withe the ALC. Therefore F$\^$-/ is eligible to be used as a tracer of pollutant which contains fluoride. Determination of F$\^$-/ in the seawater with the Dotite reagent, Alfusone, has been made by the following method: To 10 ml of water sample, 1 ml of buffer solution (pH=4.0), 8 ml of acetone, and 1ml of 10% Alfusone were added and diluted to 25ml with distilled water. After 20 minutes the absorbance at 620 nm against a reagent blank was measured. The distributions of F$\^$-/ in Jinhae Bay has been made on the basis of water samples collected from 103 different sampling stations occupied in Jinhae Bay. The water samplings, three in the spring tide and two in the neap tide, were taken from surface layer during the flood and ebb tide periods respectively. The average concentration of F$\^$-/ in the bay, except the area to which the wastewater runs off from the Chemical plant, was 1.45 ppm(1.07-6.33ppm), and that of F$\^$-/ in the plant effluent was 330ppm, occasionally up to 562 ppm. Thus high levels of F$\^$-/ in the bay are strongly correlated to the amount of effluent from the plant, and waters of Jinhae Bay contains at least 0.13% of the plant effluent.
1. 플루오르를 함유하는 배수가 바다에 유입되었을 때 플루오르화물이온을 그 추적자로 이용할 수 있다. 2. "Dotite"시약 "알풋손"에 의한 해수중의 플루오르 정량법을 검토하였다. 3. 진해만의 플루오르화물이온 농도분포를 조사하여 진해만에 플루오르를 함유하는 배수가 평균 최소한 0.13% 혼입되어 있으며 그것은 진해 모화학공장의 폐수에 기인한다. 그리고 그것이 혼입되어가는 경로를 밝혔다. 그것이 혼입되어가는 경로를 밝혔다.