Effect of Fineness of Siliceous Materials on Correction of Soil Acidity under Submerged Condition

담수시(湛水時) 규산물질(珪酸物質)들의 입도별(粒度別) 토양산도교정능력(土壤酸度矯正能力)

The liming effect of the four different siliceous materials with six grades of fineness were investigated in comparison with limestone under the submerged condition for three months, and the alkalinity extracted by 0.07N-EDTA and N-NaOAc solutions were determined to evaluate the neutralizing power of these materials. 1. Fused phosphate took 20 days with finer particles than 60 mesh (Tyler), 34 days with -40+48 mesh particles and 84 days with -20+25 mesh particles to reach the pH 5.5 from pH 4.0 of initial soil pH. These adjusted soil acidities were less 1.0-0.5 unit of pH compared with the pH of particles of limestone. 2. The basic reduction furnace slag increased the pH value to 5.5 in the finer particles than 100 mesh, but the other coarse particles appeared to have slow changes of the soil acidity to pH 4.5-4.7 for the three months. Wollastonite didn't affect the increase of soil pH in coarser particles than 25 mesh whereas other finer particles increased upto pH 4.5-5.0. Blast furnace slag is definitely slower through all sizes of particles. 3. In the relationship between the adjusted soil acidities and alkalinities dissolved in EDTA and NaOAc solution, NaOAc-alkalinity agreed quite closely to the activity of neutralizing value of silicates and limestone containing fineness of particles. The correlation coefficients between the amended soil acidities and NaOAc-alkalinities were stabilized with high significance at the 8 days after water logging and 16 days with the EDTA-alkalinities.

담수상태하(湛水狀態下)에서 수종(數種) 규산물질(珪酸物質)의 입도별(粒度別) 토양산도교정능력(土壤酸度矯正能力)을 시기별(時期別)로 비교(比較)하고 EDTA 용액(溶液)과 NaOAc 용액(溶液) 침출(浸出)알카리분(分)이 이들 물질(物質)의 토양산도교정능력(壤酸度矯正能力)을 가늠할 수 있는지 검토(檢討)한 결과(結果) 1. 용성인비(熔成燐肥)는 pH5.5에 이르는 기간(期間)이 60일(日) 보다 작은 입자(粒子)는 20일(日), 40~48일(日)에서는 34일(日), 20~25일(日)은 84일(日)이 소요(所要)됐으며 같은 크기의 석회석립자(石灰石粒子)의 교정산도(矯正酸度)보다 pH 치(値)가 약 1.0~0.5 정도(程度) 낮았다. 2. 광재(鑛滓) I(Basic reduction furnace slag)는 100보다 작은 입자(粒子)는 pH5.5까지 교정(矯正)되나 이보다 큰 입자(粒子)는 pH $4.5{\pm}0.5$ 범위(範圍)에서 머물고, 규회석(珪灰石)은 25일(日) 보다 큰 입자(粒子)는 효과가 없고 40일(日)보다 작은 입자(粒子)는 pH 4.5~5.0 까지 밖에 미치지 못하며, 광재 II(Blast furnace slag)는 입도(粒度)의 크기에 큰 영향(影響)을 받지 않고 매우 미약(微弱)한 효과를 보였다. 3. 각재료(各材料) 및 입도별(粒度別) 교정산도(矯正酸度)와 EDTA 용액(溶液) 및 NaOAc 용액(溶液) 침출(浸出)알카리분(分)과의 관계(關係)는 NaOAc 용액(溶液) 침출(浸出)알카리분(分)이 EDTA 용액침출(溶液浸出)알카리분(分)보다 토양교정산도(土壤矯正酸度)와 더욱 밀접(密接)한 관계(關係)를 나타내며, 시기별(時期別)로 NaOAc 침출(浸出)알카리분(分)은 담수후(湛水後) 8일(日), EDTA 침출(浸出)알카리분(分)은 16일(日) 이후(以後)에 상관계수(相關係數)가 고정(固定)되었다.