Mechanical Degradation of Polymers in Dilute Solutions. The Influence of the Temperature on the Scission

稀薄溶液에서의 polymer의 機械的切斷. 切斷에 미치는 온도의 영향

  • Published : 1971.06.30

Abstract

The mechanical degradation of poly (${\alpha}$-methyl styrene) in several mixed solvents (toluene-n-butyl alcohol, toluene-sec-butyl alcohol, toluene-kerosene, toluene-methyl ethyl ketone), from $1^{\circ}C to $45^{\circ}C$, was studied using the capillary flow method. The velocity constant of scission reaction (k) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$] at each temperatures. As results, mechanical degradation of polymer in dilute mixed solutions is affected by composition of solvents around the polymer chains.

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References

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