대한화학회지 (Journal of the Korean Chemical Society)

  • 제15권2호
  • /
  • Pages.85-93
  • /
  • 1971
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

여러온도에서 염화아닐린늄의 수용액중에서의 분몰랄부피 및 점도에 관한 연구

Partial molal volume and viscosity of anilinium chloride in water at various temperatures

  • 조병린 (인하대학교 공과대학 화학공학과) ;
  • 이영자 (인하대학교 공과대학 화학공학과) ;
  • 김광호 (인하대학교 공과대학 화학공학과)
  • Byung-Rin Cho (Dept. of Chem. Eng., Inha Inst. of Technology) ;
  • Young-Ja Lee (Dept. of Chem. Eng., Inha Inst. of Technology) ;
  • Kwang-Ho Kim (Dept. of Chem. Eng., Inha Inst. of Technology)
  • 발행 : 1971.04.30
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초록

Apparent molal valumes ${\phi}_v$ and relative viscosities ${\eta}_r$ of aqueous solutions of anilinium chloride have been determined at two degree intervals from 20 to $50^{\circ}C$ in the molar concentration range 0.003 < C < 0.4. The results are discussed in terms of partial molal volumes $\={V}^{\circ}$, deviations from the Debye-H$\''{u}$ckel limiting law, partial molal expansibilities $\={E}^{\circ}$, viscosity B coefficients calculated from the Jones-Dole equation, and energy of activation for viscous flow. In aqueous solution, anilinium chloride was found to be a weak structure-maker due to its hydrophobic group.

키워드

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