Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Surface Tension of Molten Salts and Strong Electrolyte Solutions

용융염과 강전해질용액의 표면장력

  • Paek, Woo-Hyun (Department of Chemistry, Dong Guk University and Korea Institute of Science and Technology) ;
  • Sung, Yong-Kil (Department of Chemistry, Dong Guk University and Korea Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry, Dong Guk University and Korea Institute of Science and Technology)
  • 백우현 (동국대학교 화학과 한국과학기술연구소) ;
  • 성용길 (동국대학교 화학과 한국과학기술연구소) ;
  • 전무식 (동국대학교 화학과 한국과학기술연구소)
  • Published : 19700900
Download PDF
⟨ Previous Next ⟩

Abstract

A theory of surface tension developed by using the approximation that the surface of liquids consists of a monomolecular layer has been applied to the molten salts (NaCl, KCl, NaBr, KBr) and the strong electrolyte solutions. By considering that the ionic forces are the long-range forces and with the use of the partition functions developed, the surface tension of molten salts and strong electrolyte solutions has been calculated. The results show good agreement between theory and experiment at various temperatures and over a wide concentration ranges (0.1-4.0m)

Keywords

References

  1. Molten Salts Handbook G.J. Janz
  2. Handbook of Chemistry N.A. Lange
  3. J. Am. Chem. Soc. v.63 G. Jones;W.A. Bay
  4. J. Am. Chem. Soc. v.64 G. Jones;W.A. Bay
  5. J.Chem. Phys. v.34 H. Reiss;S.W. Mayer
  6. J. Chem. Phys. v.2 L. Onsager;N.N.T. Samaras
  7. J. Chem. Phys. v.17 J.G. Kirkwood;F.P. Buff
  8. Trans. Faraday Soc. v.37 J.W. Belton;M.G. Evans
  9. Trans. Faraday Soc. v.36 J.E. Lennard-Jones;J. Corner
  10. Trans. Faraday soc. v.44 J. Corner
  11. J. Chem Phys. v.49 I. Prigogine;L. Saraga
  12. J. Chem. Phys. v.38 S.W. Mayer
  13. J. Phys. Chem. v.67 S.W. Mayer
  14. Progr. Intern. Res. Thermodynamic Transport Properties v.2 S. Chang;T. Ree;H. Eyring;I. Matzner
  15. J. Chem. Phys. v.41 T.S. Ree;T. Ree;H. Eyring
  16. J. Chem. Phys. v.46 W.C. Lu;M.S. Jhon;T. Ree;H. Eyring
  17. Proc. Natl. Acad. Sci. (U.S) v.47 H. Eyring;T. Ree
  18. J. Chem. Educ. v.40 H. Eyring;R.P. Marchi
  19. Significant Liquid Structures H. Eyring;M.S. Jhon
  20. J. Chem. Phys. v.49 W.C.Lu;T. Ree;V.G. Gerrad;H. Eyring
  21. Symposium, A.C.S., South eastern regional meeting M.S. Jhon;H. Eyring(et al.)
  22. Z. Phys. v.24 O. Emersleben
  23. Proc. Natl. Acad. Sci. (U.S.) v.64 M.S. Jhon;H. Eyring
  24. Structure of Aqueous Electrolyte Solutions and the Hydration of Ions O.Y. Samoilov
  25. The Physico-Chemical Constants of Binary Systems in Concentrated Solutions v.III J. Timmerman