炭化水素內에서의 Alkyl Iodides의 光分解에서 $II^{131}$과 Alkyl Iodides 間의 交換反應

Exchange Reaction Between Alkyl Iodides and $II^{131}$ in the Photolysis of Alkyl Iodides in Hydrocarbon

  • Choi, Jae-Ho (Chemistry Division, Atomic Energy Research Institute)
  • 발행 : 19660300

초록

The rate of exchange of I atom between alkyl iodides(ethyl or methyl iodide) and $I_2$ in n-hexane have been determined using $II^{131}$. It is found that the escape of $CH_3$ radicals from a solvent cage is faster than $C_2H_5$ radicals and that photolysis of $C_2H_5I$ is almost identical to that in the case of $CH_3I$.

키워드

참고문헌

  1. J. A. C. S. v.79 S. Aditya;J. E. Willard
  2. J. A. C. S. v.79 R. L. Strong;J. E. Willard
  3. ph. D. thesis R. H. Luebbe;J. E. Willard
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  5. Cage effect in the photolysis of $C_2H_5I$ F. Johnston;J. E. Willard