Mechanism of Quenching by Dimethylanilines in Liquid Scintillation Counting

Liquid Scintillation Counting 에서의 Dimethylaniline 에 依한 消光機構

  • 이익춘 (原子力硏究所 化學硏究室)
  • Published : 19640600

Abstract

Quenching constants, q, determined for N,N-dimethylanilines by liquid scintillation counting indicate that the quenching involves an energy transfer process to these compounds causing strong n-${\pi}$ interaction within the quencher molecule, which is then followed by an non-radiative degradation of the excitation energy to ground state.

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References

  1. J. Appl. Rad. and Isotopes v.1 F. N. Hayes
  2. Liquid scintillation counting R. K. Swank;C. G. Bell, Jr(ed.);F. N. Hayes(ed.)
  3. The Element of Physical Chemistry S. Glasstone
  4. Int. J. Appl. Rad. and Isotopes v.1 V. N. Kerr;F. N. Hayes;D. G. Ott
  5. Liquid scintillation counting C-T Peng
  6. Ph. D. Thesis Univ. of London Ikchoon Lee
  7. 化學의領城 v.17 no.2 又賀昇
  8. Liquid scintillation counting H. Kallman;M. Furst
  9. J. Am. Chem. Soc. v.82 H. Linschitz;L. Pekkarinen
  10. J. Chem. Phys. v.34 J. M. Nosworthy;J. L. Magee;M. Burton
  11. J. Am. Chem. Soc. v.82 H. Tsubomura;R. S. Mulliken
  12. Steric Effects in Conjugated Systems B. M. Wepster;G. M. Gray(ed.)
  13. Disc. Faraday Soc. v.9 M. Kasha
  14. Bull. Chem. Soc. Jan. v.30 N. Mataga;S. Tsuno
  15. J. Chem. Phys. v.24 R. C. Sangster;J. W. Irvine
  16. J. Chem. Soc. J. N. Murrell