한국동물학회지 (The Korean Journal of Zoology)
- 제7권2호
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- Pages.1-5
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- 1964
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- 0440-2510(pISSN)
Triglycine 수용액에 미치는 감마선의 영향 3. 감마선에 의한 분해산물에 관하여
The Effect of Gamma-Irradiation on Aqueous Solutions of Triglycine 3. Mechanism for Gamma-ray Induced Degradation Products
초록
산소 용존하의 triglycine 수용액을
Carbonyl compounds, glycine, ammonia, carbon dioxide and hydrogen have been identified in gamma-irradiated oxygenated aqueous solutions of triglycine. The reactions occurring in this system are postulated only by representing the initial process and the final products. The triglycine molecule undergoes a reaction to form an intermediate giving rise to carbonyl compounds and acid amides. These compounds are decomposed to acetamide, glycine, glyoxylic acid, formic acid, oxalic acid, ammonia, and carbon dioxide by free radical attack in the primary and/or secondary reactions. It is also possible that the unrecognized reactions may give rise to products formed by radical-radical combinations. Satisfactory material balance for all the products have to wait until the completion of a study now in progress.ogress.
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