한국염색가공학회:학술대회논문집 (Proceedings of the Korean Society of Dyers and Finishers Conference)
- 한국염색가공학회 2011년도 제44차 학술발표회
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- Pages.67-67
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- 2011
프탈로시아닌 유도체 합성 및 광학응답특성 연구
- 발행 : 2011.03.10
초록
Recently, Phthalocyanine dye has attentions due to their excellent photochemical properties and used to optical applications such as chemical sensors. And azo groups can change photochemical properties in the UV irradiation because their molecualr structure reverse cis-trans isomer and changes cooperative motion, aggregation and so on. In this study, we synthesized the azo compound between amino pyridine and phenol. this azo derivative used the combination with 3-nitro phthalonitrile and makes phthalocyanine structure through the synthesis with 1,8-diazabicyclo[5.4.0]undec-7-ene(DBU), zinc acetate. Finally, we synthesized a new photoswiching dye zinc-phthalocyanine azo compound. This compound was studied by phothoswichiing phenomenon by UV irradiation and analyzed molecular aggregation through the SEM images.
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