카바졸 전자 공여기를 포함한 D-${\pi}$-A 유도체의 결정 구조

  • Kim, Byung-Soon (Graduate School of Environmental and Information Sciences, Yokohama National University) ;
  • Kim, Su-Ho (Dept. of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Matsumoto, Shinya (Graduate School of Environmental and Information Sciences, Yokohama National University) ;
  • Son, Young-A (Dept. of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 발행 : 2011.03.10

초록

The donor-${\pi}$-acceptor (D-${\pi}$-A) chromophoric dye system has received great attention in variety fields such as electroluminescent materials, sensors and optoelectronic devices. There are many research activities focused on the development for abovementioned application materials with the high-performance properties. In the previous work, we are reported that novel D-${\pi}$-A dye, 2-[4-(9H-carbazol-9-yl)benzylidene]-2,3-dihydroinden-1-one, is successfully attained and exhibited a positive fluorescence solvatochromism. In this work, the molecular structure and packing geometry of 2-[4-(9H-carbazol-9-yl)benzylidene]-2,3-dihydroinden-1-one was discussed by their conformational structure. Their single yellow prism crystal having approximate dimensions of $0.30{\times}0.10{\times}0.10$ mm was carried out with a Rigaku RAXIS RAPID imaging plate area detector with graphite monochromated $CuK_{\alpha}$ radiation. Their crystal structure were solved by using the CrystalStructure crystallographic software package.

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