Proceedings of the KAIS Fall Conference (한국산학기술학회:학술대회논문집)
- 2011.05a
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- Pages.323-326
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- 2011
Selective alkylation of alkylaromatics over HZSM-5 zeolite synthesised in fluoridemedium
Fluoridemedium에서 HZSM-5 제올라이트를 이용한 알킬아로마틱의 선택적 알킬화
- Hemalatha, Pushparaj (Department of Chemical Engineering, Hanseo University) ;
- Venkatachalam, Kandan (Department of Chemical Engineering, Hanseo University) ;
- Ganesh, Mani (Department of Chemical Engineering, Hanseo University) ;
- Peng, Mei-Mei (Department of Chemical Engineering, Hanseo University) ;
-
Lee, Joo-Bo
(Department of Chemical Engineering, Hanseo University)
;
-
Jang, Hyun-Tae
(Department of Chemical Engineering, Hanseo University)
- 푸시파라지 헤마라다 (한서대학교 화학공학과) ;
- 칸단 벤카타찰람 (한서대학교 화학공학과) ;
- 마니가니쉬 (한서대학교 화학공학과) ;
- 팽메이메이 (한서대학교 화학공학과) ;
-
이주보
(한서대학교 화학공학과)
;
-
장현태
(한서대학교 화학공학과)
- Published : 2011.05.27
Abstract
HZSM-5, synthesized in fluoride medium, showed high selectivity for the formation of 1,4-diethylbenzene (1,4-DEB) in the vapour phase ethylation of ethylbenzene (EB) with ethanol and hence becomes a convenient eco-friendly substitute for hazardous mineral acid catalysts. De-ethylation of EB to benzene was also minimized over this catalyst. As the medium pore size and presence of weak and medium acid sites might be the cause of such benefits, fluoride mediated synthesis of ZSM-5 is proven to be advantageous for para-selective alkylation of alkyl aromatics.
Keywords