Proceedings of the Korean Vacuum Society Conference (한국진공학회:학술대회논문집)
- 2010.08a
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- Pages.63-63
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- 2010
Abnormal Work Function Modification at the Interface between Organic Molecule and Solid Surfaces
- Kim, Ji-Hoon (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University) ;
- Seo, Jae-Won (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University) ;
- Kang, Hye-Seung (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University) ;
- Kim, Jeong-Kyu (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University) ;
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Kim, Jeong-Won
(Korea Research Institute of Standards and Science) ;
- Lee, Han-Gil (Department of Chemistry, Sookmyung Woman's University) ;
- Kwon, Young-Kyung (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University) ;
- Park, Yong-Sup (Department of Physics and Research Institute for Basic Sciences, Kyung Hee University)
- Published : 2010.08.18
Abstract
Using both experimental and theoretical approaches, we have investigated the adsorption properties of an organic molecule (HATCN), which is used in OLEDs as an efficient hole injection layer, on metal and inert surfaces. We have also studied the structural and electronic properties of such interfaces and the dependences on deposition thickness. We have observed different trends in work function changes with different surfaces. Our photoelectron spectroscopic measurements have revealed an abnormal phenomenon in HATCN on a metal (Cu) surface: the work function decreases at lower coverage (~monolayer) of HATCN on a metal (Cu) surface, but it increases back and becomes higher than that of a bare Cu surface at higher coverage. It has, on the contrary, been observed that the work function of graphene surface just increases as the HATCN coverage increases. Our first-principles density functional calculations has not only verified our experimental observations, but also disclosed the underlying mechanism of such abnormal and different work function behaviors. We have found that the change in work function results from mutual polarization induced by the geometrical deformation and the bond dipole formed at the interface due to the charge redistribution. At low coverage of HAT-CN on Cu substrate, the former reduces the work function significantly by pulling down the vacuum level, while the latter tends to push up the vacuum level resulting in the work function increase.
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