Proceedings of the Korean Vacuum Society Conference (한국진공학회:학술대회논문집)
- 2010.02a
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- Pages.367-367
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- 2010
Stereoselective attachment of S-Proline on Ge(100)
- Youn, Young-Sang (Department of Chemistry, Molecular-Level Interface Research Center, KAIST) ;
- Kim, Ki-Jeong (Beamline Research Division, Pohang Accelerator Laboratory (PAL)) ;
- Kim, Bong-Soo (Beamline Research Division, Pohang Accelerator Laboratory (PAL)) ;
- Lee, Hang-Il (Department of Chemistry, Sookmyung Women's University) ;
- Kim, Se-Hun (Department of Chemistry, Molecular-Level Interface Research Center, KAIST)
- Published : 2010.02.17
Abstract
The adsorption configurations of S-proline on Ge(100) were studied using scanning tunneling microscopy (STM), density functional theory (DFT) calculations, and high-resolution core-level photoemission spectroscopy (HRCLPES). We identified three adsorption structures of S-proline on Ge(100) through analysis of the STM images, DFT calculations, and HRCLPES results: (i) an 'intrarow O - H dissociated and N dative bonded structure', (ii) an 'O - H dissociation structure', and (iii) an 'N dative bonded structure'. Moreover, because adsorption through the N atom of S-proline produces a new chiral center due to symmetry reduction by N dative bonding, the adsorption configurations have either (R,S) or (S,S) chirality, yielding an (R,S)-'intrarow O - H dissociated and N dative bonded structure' and an (R,S)-'N dative bonded structure', with a preference for reaction at the Re face. This work presents a novel method for generating stereoselective attachment using S-proline molecules adsorbed onto a Ge(100) surface.
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