ANTICORROSION PROPERTIES OF SIOC COATED SUS-316

  • Published : 2009.11.05

Abstract

The ceramic coatings on metallic materials have attracted by many researchers due to the chemical inertness of ceramic materials. In such aspect, SiOC is a promising material tobe used as protective coating layer on metallic materials due to its outstanding thermal stability and chemical inertness. In this research, SiOC coating was carried out onto SuS-316 substrate using Cl free preceramic polymers such aspolyphenylcarbosilane. 20% of polymethylphenylsilane in cyclohexane solution was coated onto metal surface by dip coating method. Thermal oxidation was carried out at $200^{\circ}C$ for crosslink of the preceramic polymer and the sample was pyrolysized at $800^{\circ}C$ under argon to convert the preceramic polymer to amorphous SiOCx state. The microstructure of the SiOCx film after pyrolysis was investigated using FE-SEM. Corrosion resistance of SiOC coated SuS-316 substrate has been investigated using 5% HCl solution at 25, 40, 60 and $80^{\circ}C$ for 7days. The data revealed that the corrosion resistance increased with SiOC coating on SuS-316 substrate.

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