한국염색가공학회:학술대회논문집 (Proceedings of the Korean Society of Dyers and Finishers Conference)

한국염색가공학회 (The Korean Society of Dyers and Finishers)
권호 표지

VS계 반응염료 가수분해반응의 열역학적 해석

Thermodynamic Analysis on the Hydrolysis Reaction of Vinylsulfonyl Reactive Dyes

  • 권혁성 (성균관대학교 공과대학 텍스타일시스템공학과) ;
  • 전영실 (성균관대학교 공과대학 텍스타일시스템공학과) ;
  • 남성우 (성균관대학교 공과대학 텍스타일시스템공학과) ;
  • 김인회 (성균관대학교 공과대학 텍스타일시스템공학과)
  • 발행 : 2008.04.11
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초록

The hydrolyses of ten VS dyes were examined at 40$^{\circ}C$, 50$^{\circ}C$, and 60$^{\circ}C$ and the kinetic parameters were estimated. The values of free energy, enthalpy and entropy of hydrolysis and reaction with cellulose for VS dyes were calculated. The linear relationship exist between the enthalpy and entropy. The structure and entropy of VS dyes gave a effect on the dimerization for VS reactive dyes. The VS dyes have small value of entropy were formed dimer. It was confirmed that no dimer form for m-substituted VS dyes. There were similarities among various reactions including homo- and mixed dimerization.

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