Proceedings of the Polymer Society of Korea Conference (한국고분자학회:학술대회논문집)
- 2006.10a
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- Pages.377-377
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- 2006
Macroalkoxyamines and macroRAFT agents based on polyethylene for the syntheses of polyolefin based polar block copolymers
- Lopez R. Godoy (Laboratoire de Chimie et Procedes de Polymerisation) ;
- Boisson C. (Laboratoire de Chimie et Procedes de Polymerisation) ;
- D'Agosto F. (Laboratoire de Chimie et Procedes de Polymerisation) ;
- Spitz R. (Laboratoire de Chimie et Procedes de Polymerisation) ;
- Boisson F. (Service de RMN de la Federation des Polymeristes Lyonnais) ;
- Gigmes D. (UMR 6517 Chimie, Biologie et Radicaux Libres, Equipe Chimie Radicalaire, Organique et Polymeres de Specialite CNRS/Universites d'Aix-Marseille) ;
- Bertin D. (UMR 6517 Chimie, Biologie et Radicaux Libres, Equipe Chimie Radicalaire, Organique et Polymeres de Specialite CNRS/Universites d'Aix-Marseille)
- Published : 2006.10.13
Abstract
Alkoxyamine and thiocarbonyl thio end capped polyethylene (PE) chains were synthesized using a direct and simple approach consisting in reacting di(polyethylenyl)magnesium (PE-Mg-PE) chains with a range of nitroxides and disulfides of thiocarbonyl thio compounds. PE-Mg-PE compounds were prepared by a catalyzed chain growth reaction of ethylene on nbutyloctylmagnesium (BOMg) with a neodymocene complex
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