한국고분자학회:학술대회논문집 (Proceedings of the Polymer Society of Korea Conference)

한국고분자학회 (The Polymer Society of Korea)
권호 표지

Construction of Ortho-Phenylene-Bridged Cp/Amido Titanium Complexes and Their Ethylene/Apha-Olefin Copolymerizations

  • Cho, Dae-Joon (Department of Molecular Science and Technology, Ajou University) ;
  • Wu, Chun-Ji (Department of Molecular Science and Technology, Ajou University) ;
  • Lee, Bun-Yeoul (Department of Molecular Science and Technology, Ajou University)
  • 발행 : 2006.10.13
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초록

A Suzuki-coupling route is developed for preparation of ortho-phenylene-bridged Cp/amido complexes, one of which shows higher activity, higher 1-hexene incorporation, and higher molecular weight than the silylene-bridged standard CGC $[Me_{2}Si({\eta}^{5}-Me_{4}Cp)(N^{t}Bu)]TiCl_{2}$.

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