Proceedings of the Polymer Society of Korea Conference (한국고분자학회:학술대회논문집)
- 2006.10a
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- Pages.104-105
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- 2006
Creation of New Reactions of Oxetanes and their Application to Polymer Synthesis
- Nishikubo, Tadatomi (Department of Applied Chemistry, Faculty of Engineering, Kanagawa University) ;
- Kudo, Hiroto (Department of Applied Chemistry, Faculty of Engineering, Kanagawa University)
- Published : 2006.10.13
Abstract
We succeeded the synthesis of new functional polymers by novel ring-opening addition reactions of bis(oxetane)s with diacyl chlorides, di(active ester)s, and di(carboxylic acid)s using quaternary onium salts as catalysts at appropriate conditions. Hyperbranched polyesters with many pendant hydroxy groups were also synthesized by the polyaddition of bis(oxetane)s with tricarboxylic acid, or by the self-polyadditions of
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