Electrospun TiO2 Electrodes for Quasi-Solid State Dye- sensitizedSolar Cell

  • Song, Mi-Yeon (Optoelectronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Ahn, Young-Rack (Optoelectronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Jo, Seong-Mu (Optoelectronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Kim, Dong-Young (Optoelectronic Materials Research Center, Korea Institute of Science and Technology)
  • Published : 2006.10.13

Abstract

[ $TiO_2$ ] single crystalline nanorods are prepared from electrospun fibers which are composed of nanofibrils with an island-in-a-sea morphology. The mechanical pressure produces each fibril into nanorods which are converted to anatase single crystals after calcinations. HRTEM shows that the (001) plane is growing along the longitudinal direction of the rod. In this work, the nanorod electrode provides the efficient photocurrent generation in a quasi-solid state dye-sensitized solar cells (DSSCs) using highly viscous PVDF-HFP based gel electrolytes. The overall converision efficiency of the $TiO_2$ nanorods shows 6.2 % under $100\;mW/cm^2$ (AM 1.5G) illumination.

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