폐플라스틱 필름의 액상 열분해 특성에 관한 연구

Liquid-phase Thermal Degradation Properties of Waste Plastic Film

  • 황택성 (충남대학교 공과대학 화학공학과) ;
  • 김영수 (충남대학교 공과대학 화학공학과) ;
  • 강태원 (공주대학교 공과대학 화학공학과) ;
  • 황의환 (천안공업대학 신소재응용화학과)
  • Hwang, T.S. (Department of Chemical Engineering, College of Engineering, Chungnam National University) ;
  • Kim, Y.S. (Department of Chemical Engineering, College of Engineering, Chungnam National University) ;
  • Kang, T.W. (Department of Chemical Engineering, College of Engineering, Kongju National University) ;
  • Hwang, E.H. (Department of Advenced Material & Chemical Technology, Cheonan National Technical College)
  • 발행 : 2003.10.15

초록

In this study, the thermal degradation process has been investigated at various reaction temperature$(350{\sim}400^{\circ}C)$ and times$(30{\sim}120\;min)$ in order to recycle waste plastic films as solid state wax. Waste plastic films were easily melted by adding a small amount of waxes. The effects of wax addition and nitrogen flow rate on their thermal degradation properties were investigated. FT-IR, GPC and viscometer were used to analyze properties of the solid wax including the structure, molicular weight distribution and melt viscosity. The average molecular weight of solid wax was decreased with increasing the reaction time, temperature and amount of wax added, Also, the viscosity of solid wax decreased with increasing the stirring speed at a constant reaction temperature and time, and its viscosity got close to zero above $390^{\circ}C$.

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