한국섬유공학회:학술대회논문집 (Proceedings of the Korean Fiber Society Conference)
- 한국섬유공학회 2003년도 가을 학술발표회 논문집
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- Pages.177-178
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- 2003
아크릴로니트릴의 중합시 1,2-DACH의 첨가가 PAN의 입체규칙성에 미치는 영향에 관한 DFT 연구
A Density Functional Study on the Addition Effect of 1,2-DACH on the Stereoregularity of PAN in the Polymerization of AN
- Cho, Eun-Kyung (Envior-Polymer Design Laboratory, Hyperstructured Organic Materials Research enter(HOMRC), School of Materials Science and Engineering, Seoul National University) ;
- Park, Chong-Rae (Envior-Polymer Design Laboratory, Hyperstructured Organic Materials Research enter(HOMRC), School of Materials Science and Engineering, Seoul National University)
- 발행 : 2003.10.01
초록
Many researchers have made efforts to control the stereoregularity in radical polymerization of vinyl monomers because the physical and chemical properties of the polymer are significantly affected by the stereostructure.[1]-[4] In general, monomer design, reaction conditions(e.g. solvent, temperature, and monomer concentration), and additives can alter the stereochemistry of the radical polymerization of acrylic monomer. (omitted)
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