Proceedings of the Korean Fiber Society Conference (한국섬유공학회:학술대회논문집)
- 2003.10b
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- Pages.177-178
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- 2003
A Density Functional Study on the Addition Effect of 1,2-DACH on the Stereoregularity of PAN in the Polymerization of AN
아크릴로니트릴의 중합시 1,2-DACH의 첨가가 PAN의 입체규칙성에 미치는 영향에 관한 DFT 연구
- Cho, Eun-Kyung (Envior-Polymer Design Laboratory, Hyperstructured Organic Materials Research enter(HOMRC), School of Materials Science and Engineering, Seoul National University) ;
- Park, Chong-Rae (Envior-Polymer Design Laboratory, Hyperstructured Organic Materials Research enter(HOMRC), School of Materials Science and Engineering, Seoul National University)
- Published : 2003.10.01
Abstract
Many researchers have made efforts to control the stereoregularity in radical polymerization of vinyl monomers because the physical and chemical properties of the polymer are significantly affected by the stereostructure.[1]-[4] In general, monomer design, reaction conditions(e.g. solvent, temperature, and monomer concentration), and additives can alter the stereochemistry of the radical polymerization of acrylic monomer. (omitted)
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