Solution-Phase Synthesis of a Library of Biaryl Amides Using Girard′s reagent T as an Acid Chloride Scavenger

  • Kim, Shin-Ae (Natural Products Research Institute College of Pharmacy, Seoul National University) ;
  • Kim, Sang-Hee (Natural Products Research Institute College of Pharmacy, Seoul National University) ;
  • Ko, Hyo-Jin (Natural Products Research Institute College of Pharmacy, Seoul National University) ;
  • Lee, Tae-Ho (Natural Products Research Institute College of Pharmacy, Seoul National University)
  • 발행 : 2002.10.01

초록

An efficient process for the solution-phase synthesis of biaryl amides has been developed. Girard's reagent T. an inexpensive scanvenger. was found to be very efficient in trapping excess aromatic acid chlorides. resulting in water soluble by-products. which were easily removed from the products by liquid-liquid extraction. The ease of use. and the excellent purity of the amide libraries obtained are important features of this protocol. (omitted)

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