Proceedings of the Korea Crystallographic Association Conference (한국결정학회:학술대회논문집)

Korean Crystallographic Association (한국결정학회)
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Synthesis and structure of $[Cp^*Rh({\eta}^6-2,6-diisopropylaniline)](OTF)_2$

  • 백지영 (성균관대학교 이과대학 화학과) ;
  • 한원석 (성균관대학교 이과대학 화학과) ;
  • 이순원 (성균관대학교 이과대학 화학과)
  • Published : 2002.11.01
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Abstract

Reaction of [$Cp^*Rh(NO_3)OTf$] (1) with 2,6-diisopropylaniline under argon led to the formation of $[Cp^*Rh({\eta}^6-2,6-diisopropylaniline)](OTF)_2$, (2). Compound 2 was characterized by NMR, IR, elemental analysis, and X-ray diffraction. Crystallrographc data for 2: orthorhombic, space group $Cmc2_1$, $a=19.850(16){\AA}$, $b=9.870(8){\AA}$, $c=15.774(13){\AA}$, Z = 4, $R(wR_2)=0.0362(0.0938)$.

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