DNAPL Removal Mechanisms and Mass Transfer Characteristics during Cosolvent-Air Flooding

  • Jeong, Seung-Woo (National Research Council Research Associate) ;
  • A. Lynn Wood (U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, Subsurface Protection and Remediation Division) ;
  • Lee, Tony R. (U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, Subsurface Protection and Remediation Division)
  • Published : 2002.04.01

Abstract

The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass transfer rate coefficients during CA flooding. DNAPL removal mechanisms were examined by evaluating the effects of air flow rate and DNAPL solubility and visually documented at a pore-scale. Two serial processes, immiscible displacement and dissolution, were experimentally and visually documented during CA flooding. Mass transfer rate coefficients (K) were computed from the data showing PCE saturation versus time. Results showed that CA floods exhibited higher K values than cosolvent floods without concurrent air injection. (This document has not been subjected to Agency review and therefore does not necessarily reflect the views of the Agency, and no official endorsement should be inferred.)

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