폴리머 애자용 EPDM 고무의 자외선 열화특성

UV Aging on EPDM rubber for use in polymer Insulators

The effects of accelerated UV radiation on EPDM used for a polymeric insulator were investigated by contact angle, surface voltage decay after corona charging, SEM-EDX, ATR-FTIR and XPS. EPDM occurs as loss of hydrophobicity by UV treatment, which followed by surface cracking and chalking. The surface voltage decay on UV-treated EPDM show that the shorter decay time corresponded to the treated samples with a longer UV exposure time. The surface oxygen and aluminum content were found to increase and carbon decrease, as is observed in EDX analysis. The ATR-FTIR and XPS indicated that C-C and C-H groups decreased and the highly oxidized carbon bonds such as C-O, C=O and O-C=O increase with time. Also, the effects of surface charges on hydrophobicity based on our results is discussed.