광기능성 덴드리머의 계면반응 특성

Characteristics of Interface Response of Optical Functionalized Dendrimer

  • 손정호 (동아대학교 전기공학과 & CIIPMS) ;
  • 신훈규 (동아대학교 전기공학과 & CIIPMS) ;
  • 김병상 (동아대학교 전기공학과 & CIIPMS) ;
  • 권영수 (동아대학교 전기공학과 & CIIPMS)
  • Son, J.H. (Dept. of Electrical Eng. & CIIPMS, Dong-A University) ;
  • Shin, H.K. (Dept. of Electrical Eng. & CIIPMS, Dong-A University) ;
  • Kim, B.S. (Dept. of Electrical Eng. & CIIPMS, Dong-A University) ;
  • Kwon, Y.S. (Dept. of Electrical Eng. & CIIPMS, Dong-A University)
  • 발행 : 2001.11.03

초록

We synthesized dendrimers containing light switchable units such as azobenzene group at the air/water interface. Their chemical structure was verified by using NMR study and UV spectroscopy. We firstly investigated the monolayer behavior and by light irradiation using $\pi$-A isotherm at the air/water interface. As a result, the monolayer of dendrimer with azobenzene group showed the reversible photo-switching behavior by the isomerization of azobenzene group in their periphery. This suggests that optical behavior and morphological change are affected by the functional group and the symmetric chain.

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