열처리 조건에 따른 $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$ 유리의 전기화학적 특성변화

Electrochemical properties of $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$ Glass by Heat-treatment

  • 김윤선 (전남대학교 전기공학과) ;
  • 손명모 (대구공업대학 세라믹신소재과) ;
  • 이헌수 (대구공업대학 세라믹신소재과) ;
  • 구할본 (전남대학교 전기공학과)
  • 발행 : 2001.07.01

초록

Instead of a solution technigue producing amorphous LiV$_3$O$_{8}$ form, we prepared Lithium vanadate glass by melting Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$, composition in pt. crucible and by quenching on the copper plate. From the crystallization of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$, we could abtain crystal phase, LiV$_3$O$_{8}$. The material heat-treated at lower-temperature, 25$0^{\circ}C$ was less crystalline, but had higher capacity. In present paper, we describe eletrochemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathod material.cathod material.

키워드