대한전기학회:학술대회논문집 (Proceedings of the KIEE Conference)
- 대한전기학회 1999년도 하계학술대회 논문집 D
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- Pages.1873-1875
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- 1999
전극 및 메트릭스가 인산형 연료전지의 성능에 미치는 영향
Effects of Electrode and Matrix in the PAFC Performance
- Kim, Dong-Jin (Korea Institute of Energy Research) ;
- Song, Rak-Hyun (Korea Institute of Energy Research) ;
- Lee, Byung-Rok (Korea Institute of Energy Research) ;
- Kim, Chang-Soo (Korea Institute of Energy Research) ;
- Shin, Dong-Ryul (Korea Institute of Energy Research)
- 발행 : 1999.07.19
초록
The effects of electrode and matrix in the PAFC were investigated using AC-impedance spectroscopy. The performance of PAFC was determined by changing external electronic load. AC impedance measurement was carried out as functions of phosphoric acid impregnation temperature. operating temperature and matrix coating method using various cathodes ; 20%Pt/C, 20%Pt-Ni/C, 20%Pt-Co-Ni/C, 10%Pt-Fe-Co/C, and 20%Pt-Fe-Co/C From the analysis of measured impedance data, the interfacial resistance decreased with increasing operating temperature. and with decreasing impregnation temperature. As compared with the alloy catalysts, Pt catalyst showed a lower interfacial resistance. This consist with the cell performance.
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