Corrosion of Quartz Crystal Sensors in Sea Water

항만센서용 수정진동자의 해수에 의한 부식

  • ;
  • ;
  • ;
  • A. Egawa ;
  • H. Muramatsu
  • 최광재 (동아대학교 공과대학 화학공학과) ;
  • 김영한 (동아대학교 공과대학 화학공학과) ;
  • 장상목 (동아대학교 공과대학 화학공학과) ;
  • ;
  • Published : 1998.10.01

Abstract

A quartz crystal analyzer is utilized to monitor the cmsion process of an aluminum surface of a quartz crystal by sea water. A quartz crystal having 2000${\AA}$ of aluminum layer is installed in a spedally designed cell and is in contact with an electrolyte solution. While a constant potential is applied to the cell, the resonant frequency and resonant resistance are simultaneously measured using the quartz crystal analyzer. In addition, surface topographs are taken with an atomic force microscope(AFM) and the element analysis of the surface is conducted using an energy dispersive X-ray spectrornetedEDX). The simultaneous measurement of resonant frequency and resonant resistance during the corrosion process explains the change of surface structure caused by the corrosion. The variation of resonant frequency addresses the amount surface metal dissolution. As a conclusion, it is found that a simple measurement using the quartz crystal analyzer can replace the complex monitoring employing large equipments in the investigation of a corrosion process of metal surface.

Keywords