TCNQ 유기초박막의 분자 배향 및 전기적 특성

Molecular orientation and electrical properties of TCNQ ultrathin organic films

  • 이용수 (홍익대학교 전기제어공학과) ;
  • 신동명 (홍익대학교 화학공학과) ;
  • 김태완 (홍익대학교 물리학과) ;
  • 강도열 (홍익대학교 전기제어공학과)
  • 발행 : 1997.11.01

초록

A study on the electrical conduction characteristics of the ultrathin organic films is one of the important factors for the development of molecular electronic devices. The Langmuir- Blodgett(LB) technique has recently been attracted interest as a method of the deposition ultrathin films. We hate fabricated N-docosyl N\`-methyl viologen-diTCNQ(DMVT) anion radical LB film and investigated the molecular orientation and electrical conduction characteristics. We have measured infrared transmission-reflection spectra. The alkyl chain is found to he well-ordered with the tilt angle of 13$^{\circ}$ with respect to the substrate surface normal and the TCNQ plane is tilted at 76$^{\circ}$ the surface normal. In ESR spectrum, we confirmed that a half-amplitude linewidth is clearly dependent on the incident angle, which indicates conducting species change. The in-plane conductivity of 31 lagers is approximately 1.33$\times$10$^{-6}$ S/cm. The ohmic behaviour was observed below 0.6 V, when current-voltage(I-V) characteristics was measured verically.

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